Rhombohedral calcite precipitation from CO2-H2O-Ca(OH)2 slurry under supercritical and gas CO2 media

The formation of solid calcium carbonate (CaCO3) from aqueous solutions or slurries containing calcium and carbon dioxide (CO2) is a complex process of considerable importance in the ecological, geochemical and biological areas. Moreover, the demand for powdered CaCO3 has increased considerably recently in various fields of industry. The aim of this study was therefore to synthesize fine particles of calcite with controlled morphology by hydrothermal carbonation of calcium hydroxide at high CO2 pressure (initial PCO2=55 bar) and at moderate and high temperature (30 and 90 degrees C). The morphology of precipitated particles was identified by transmission electron microscopy (TEM/EDS) and scanning electron microscopy (SEM/EDS). In addition, an X-ray diffraction analysis was performed to investigate the carbonation efficiency and purity of the solid product. Carbonation of dispersed calcium hydroxide in the presence of supercritical (PT=90 bar, T=90 degrees C) or gaseous (PT=55 bar, T=30 degrees C) CO2 led to the precipitation of sub-micrometric isolated particles (<1$\mu$m) and micrometric agglomerates (<5$\mu$m) of calcite. For this study, the carbonation efficiency (Ca(OH)2-CaCO3 conversion) was not significantly affected by PT conditions after 24 h of reaction. In contrast, the initial rate of calcium carbonate precipitation increased from 4.3 mol/h in the "90bar-90 degrees C" system to 15.9 mol/h in the "55bar-30 degrees C" system. The use of high CO2 pressure may therefore be desirable for increasing the production rate of CaCO3, carbonation efficiency and purity, to approximately 48 kg/m3h, 95% and 96.3%, respectively in this study. The dissipated heat for this exothermic reaction was estimated by calorimetry to be -32 kJ/mol in the "90bar-90 degrees C" system and -42 kJ/mol in the "55bar-30 degrees C" system

Adolescence et institution s’opposent-elles?

Après un rappel et une mise en perspective de la problématique générale des institutions, les auteurs centrent leur réflexion sur les aspects institutionnels du processus normal d'adolescence; la place des mécanismes psychopathologiques dans les transactions de certains adolescents avec les institutions; l'utilité de la formalisation en terme d'institution pour la mise en place de milieux et activités thérapeutiques.After reviewing and putting into perspective the general situation of institutions, the authors concentrate on the institutional aspects of the normal process of adolescence; the room given to psychopathological mechanisms in the transactions of certain adolescents with the institutions ; the usefulness of institutional formalization in setting up therapeutic environments and activities

Experimental microstylolites in quartz and modelling of natural stylolitic structures

International audienceExperimental microstylolites have been observed at stressed contacts between quartz grains loaded for several weeks in the presence of an aqueous silica solution, at 350 8C and 50 MPa of differential stress. Stereoscopic analysis of pairs of SEM images yielded a digital elevation model of the surface of the microstylolites. Fourier analyses of these microstylolites reveal a self-affine roughness (with a roughness exponent H of 1.2). Coupled with observations of close interactions between dissolution pits and stylolitic peaks, these data illustrate a possible mechanism for stylolite formation. The complex geometry of stylolite surfaces is imposed by the interplay between the development of dissolution peaks in preferential locations (fast dissolution pits) and the mechanical properties of the solid-fluid-solid interfaces. Simple mechanical modeling expresses the crucial competition that could rule the development of microstylolites: (i) a stress-related process, modeled in terms of the stiffness of springs that activate the heterogeneous dissolution rates of the solid interface, promotes the deflection. In parallel, (ii) the strength of the solid interface, modeled in terms of the stiffness of a membrane, is equivalent to a surface tension that limits the deflection and opposes its development. The modeling produces stylolitic surfaces with characteristic geometries varying from conical to columnar when both the effect of dissolution-rate heterogeneity and the strength properties of the rock are taken into account. A self-affine roughness exponent (Hz1.2) measured on modeled surfaces is comparable with natural stylolites at small length scale and experimental microstylolites

Comportement en fatigue de structures épaisses en matériaux composites = Fatigue behaviour of thick composite structures

National audienceCe travail traite de l'étude et la modélisation de l'endommagement par fissuration intra-laminaire dans les structures épaisses en matériaux composites sous chargements statiques et cycliques. La fissuration intra-laminaire est généralement le premier type de défaut rencontré au niveau macroscopique dans les composites stratifiés. Bien qu'elle ne soit pas catastrophique pour l'intégrité de la structure, la fissuration peut être à l'origine d'autres types de défauts beaucoup plus néfastes. Des essais de traction quasi-statiques et cycliques nous ont permis de mettre en évidence les caractéristiques de l'endommagement, notamment la fissuration intra-laminaire ainsi que les chutes de rigidité dues à l'apparition des fissures. La modélisation proposée est basée sur la Mécanique de l'Endommagement. Elle permet de décrire l'évolution de la fissuration ainsi que les chutes de rigidité associées. Le comportement du pli est supposé élastique endommageable. La loi d'évolution est écrite à l'aide de variables locales ce qui la rend totalement indépendante de la géométrie de la structure et du chargement extérieur. Le modèle écrit et identifié dans le cas d'éprouvettes droites est ensuite appliqué et validé sur une plaque trouée

Formation & Dissociation of Methane Hydrates in Sediments. Part II : Numerical modelling

5 pagesThe ForDiMHyS project is a program devoted to experimental studies and the model development of the kinetics of FORmation and Dissociation of Methane Hydrates in Sediments. The first part of the project which is presented in another paper (Bonnefoy and Herri, 2002) is designed to obtain experimental data on hydrate formation & dissociation under in-situ temperature and pressure conditions of methane hydrate in well constrained porous materials. The second part presented hereafter consists in modelling the flows inside the core; a specific numerical model has been developed to simulate the experimental set-up described in part one. The numerical model is 3D three phases and simulates the kinetics of hydrate dissociation and formation, taking into account the solubility of methane in water and the heat of phase transitions

Pharmacological disruption of insulin-like growth factor 1 binding to IGF-binding proteins restores anabolic responses in human osteoarthritic chondrocytes

Insulin-like growth factor 1 (IGF-1) has poor anabolic efficacy in cartilage in osteoarthritis (OA), partly because of its sequestration by abnormally high levels of extracellular IGF-binding proteins (IGFBPs). We studied the effect of NBI-31772, a small molecule that inhibits the binding of IGF-1 to IGFBPs, on the restoration of proteoglycan synthesis by human OA chondrocytes. IGFBPs secreted by human OA cartilage or cultured chondrocytes were analyzed by western ligand blot. The ability of NBI-31772 to displace IGF-1 from IGFBPs was measured by radiobinding assay. Anabolic responses in primary cultured chondrocytes were assessed by measuring the synthesis of proteoglycans in cetylpyridinium-chloride-precipitable fractions of cell-associated and secreted (35)S-labeled macromolecules. The penetration of NBI-31772 into cartilage was measured by its ability to displace (125)I-labeled IGF-1 from cartilage IGFBPs. We found that IGFBP-3 was the major IGFBP secreted by OA cartilage explants and cultured chondrocytes. NBI-31772 inhibited the binding of (125)I-labeled IGF-1 to IGFBP-3 at nanomolar concentrations. It antagonized the inhibitory effect of IGFBP-3 on IGF-1-dependent proteoglycan synthesis by rabbit chondrocytes. The addition of NBI-31772 to human OA chondrocytes resulted in the restoration or potentiation of IGF-1-dependent proteoglycan synthesis, depending on the IGF-1 concentrations. However, NBI-31772 did not penetrate into cartilage explants. This study shows that a new pharmacological approach that uses a small molecule inhibiting IGF-1/IGFBP interaction could restore or potentiate proteoglycan synthesis in OA chondrocytes, thereby opening exciting possibilities for the treatment of OA and, potentially, of other joint-related diseases

Fluctuations of sea-water chemistry during Gargasian (Middle Aptian) time. Data from trace-element content (Mg, Sr, Mn, Fe) in hemipelagic carbonates from La Marcouline Quarry (Cassis, SE France)

International audienceIn the Lower Aptian historical stratotype area (Cassis-La Bédoule, SE France), a geochemical study of the Gargasian (Middle Aptian) marl-limestone alternations of the La Marcouline quarry complements data already obtained from Bedoulian (Early Aptian) sediments there. Nannoconids are the main carbonate producers in both limestones and marls. Although diagenetic minerals, such as ankerite (2.5%) are present in small amounts, the trace-element content of bulk carbonate is very close to that of Nannoconus spp. so geochemical sequences can be defined. The long-term evolution of trace-element content was not affected by diagenetic processes, variations in carbonate mineralogy, or a change of carbonate producers. An increase of around 500 ppm in the strontium content of bulk carbonate occurs between the base of the Cabri zone (late Bedoulian) and the Algerianus zone (late Gargasian). This evolution is linked to fluctuations in seawater Sr/Ca ratios caused by variability in the influx of hydrothermal and river waters, by changes in the ratio of aragonite/calcite production and by shifts in sea level. The eustatic sequence Aptian 4, its parasequences and its key surfaces (sequence boundaries, maximum flooding surface) are clearly reflected in the evolution of the bulk-carbonate contents of manganese

Classification of Clouds Sampled at the Puy de Dôme Station (France) Based on Chemical Measurements and Air Mass History Matrices

A statistical analysis of 295 cloud samples collected at the Puy de Dôme station in France (PUY), covering the period 2001–2018, was conducted using principal component analysis (PCA), agglomerative hierarchical clustering (AHC), and partial least squares (PLS) regression. Our model classified the cloud water samples on the basis of their chemical concentrations and of the dynamical history of their air masses estimated with back-trajectory calculations. The statistical analysis split our dataset into two sets, i.e., the first set characterized by westerly air masses and marine characteristics, with high concentrations of sea salts and the second set having air masses originating from the northeastern sector and the “continental” zone, with high concentrations of potentially anthropogenic ions. It appears from our dataset that the influence of cloud microphysics remains minor at PUY as compared with the impact of the air mass history, i.e., physicochemical processes, such as multiphase reactivity